M. Catellani et al., SYNTHESIS AND CHARACTERIZATION OF ALKYL-SUBSTITUTED POLY[E-1,2-(2,2'-DITHIENYL)ETHYLENE]S, Synthetic metals, 62(3), 1994, pp. 223-228
3,3'-Dialkyl-substituted poly[E-1,2-(2,2'-dithienyl)ethylene]s (PDTEs)
have been synthesized and characterized. The polymers are sufficientl
y soluble in common organic solvents and have been structurally charac
terized by NMR and FT-IR spectroscopies. The polymers, doped via chemi
cal or electrochemical process, show a strong electrochromic effect. T
he films of substituted polymer are blue in the reduced form whilst th
e doped materials are quite transparent in the visible spectral region
.