RUTHENIUM CARBONYL DERIVATIVES OF LUTECIUM - MOLECULAR-STRUCTURE OF (THF)CP2LURU(CO)2CP

Authors
BELETSKAYA IP VOSKOBOINIKOV AZ CHUKLANOVA EB GUSEV AI SHESTAKOVA AK PARSHINA IN
Citation
Ip. Beletskaya et al., RUTHENIUM CARBONYL DERIVATIVES OF LUTECIUM - MOLECULAR-STRUCTURE OF (THF)CP2LURU(CO)2CP, Russian chemical bulletin, 42(3), 1993, pp. 534-538
Citations number
16
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
42
Issue
3
Year of publication
1993
Pages
534 - 538
Database
ISI
SICI code
1066-5285(1993)42:3<534:RCDOL->2.0.ZU;2-6
Abstract
The ruthenium carbonyl derivatives of lutecium (THF)Cp2LuRu(CO)2Cp (1) , THF)[1,3-(Me3Si)2C5H3]2 LuRu(CO)2Cp, and (C5Me5)2LuRu(CO)2Cp were p repared by treating Na[CpRu(CO)2] with lutecium halides in THF. An X-r ay structural investigation of 1 was performed (Mo K(alpha) radiation, 1828 reflections, R = 0.037). The crystals are monoclinic, a = 14.083 (2) angstrom, b = 8.347(2) angstrom, c = 17.331(2) angstrom, beta = 10 6.98-degrees, Z = 4, space group P2(1)/n. The Lu-Ru distance is equal to 2.955(2) angstrom.