PDCL2-CATALYZED HYDROGENOLYSIS OF A C-O BOND IN MONOARYL SULFATES BY SODIUM PHOSPHINATE IN AN AQUEOUS ALKALINE-MEDIUM

Authors
DAVYDOV DV BELETSKAYA IP
Citation
Dv. Davydov et Ip. Beletskaya, PDCL2-CATALYZED HYDROGENOLYSIS OF A C-O BOND IN MONOARYL SULFATES BY SODIUM PHOSPHINATE IN AN AQUEOUS ALKALINE-MEDIUM, Russian chemical bulletin, 42(3), 1993, pp. 573-575
Citations number
16
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
42
Issue
3
Year of publication
1993
Pages
573 - 575
Database
ISI
SICI code
1066-5285(1993)42:3<573:PHOACB>2.0.ZU;2-N
Abstract
The hydrogenolysis of the C-O bond in monoaryl sulfates by the action of an excess of NaH2PO2 in the presence of catalytic amounts of PdCl2 and KOH is studied. The reaction proceeds chemoselectively with comple te ester conversion to the corresponding arenes.