EFFECT OF PARTICLE-SIZE ON THE KINETICS OF PARTICLE DEPOSITION UNDER ATTRACTIVE DOUBLE-LAYER INTERACTIONS

The effect of particle size on the kinetics of particle deposition in the presence of attractive double layer interactions has been studied theoretically and experimentally. Particle deposition experiments were carried out with several model suspensions of positively charged late x particles and negatively charged glass beads using the packed bed co lumn technique. The model particles used in the deposition experiments covered a wide size range, from 0.08 to 2.51 mum. Experimental deposi tion rates were compared to theoretical predictions based on a numeric al solution of the convective diffusion equation with colloidal, hydro dynamic, and gravitational forces fully incorporated. Theoretical and experimental results reveal that the enhancement in particle depositio n rate (i.e., the deposition rate in the presence of double layer inte raction divided by the rate in the absence of double layer interaction ) is dependent on particle size. At low ionic strengths, the enhanceme nt in deposition rate passes through a maximum as the particle size in creases. This maximum corresponds to particles with a size around 1 mu m. It is also concluded that this maximum is determined by the interpl ay between the size of the particles and the range of the attractive d ouble layer interactions. (C) 1994 Academic Press, Inc.