A COMPARISON OF MEASUREMENTS OF DIFFUSIVITY OF HYDROGEN IN PD FOR 3 DIFFERENT DIFFUSION-ELASTIC PROCESSES

Citation
J. Cermak et al., A COMPARISON OF MEASUREMENTS OF DIFFUSIVITY OF HYDROGEN IN PD FOR 3 DIFFERENT DIFFUSION-ELASTIC PROCESSES, Zeitschrift für physikalische Chemie, 181, 1993, pp. 233-238
Citations number
16
Categorie Soggetti
Chemistry Physical","Physics, Atomic, Molecular & Chemical
ISSN journal
09429352
Volume
181
Year of publication
1993
Part
1-2
Pages
233 - 238
Database
ISI
SICI code
0942-9352(1993)181:<233:ACOMOD>2.0.ZU;2-2
Abstract
This paper represents further attempts to estimate the diffusivity of hydrogen in alpha-Pd at 50-degrees-C in the course of three different diffusion-elastic processes involving absorption, equilibration of con centrations, and desorption of hydrogen, respectively. The numerical r esults, obtained by a least-squares treatment indicate a statistically significant difference between values derived by absorption and equil ibration procedures on one hand and values obtained from desorption st udies on the other. General reasoning seems to indicate a preference f or the equilibration derived values for the hydrogen diffusion coeffic ients as the most reliable.