Runoff and pond water samples from a container nursery that recycles w
ater for irrigation were tested for movement of herbicides from the si
te of application. Residues of oryzalin 4-(dipropylamino)-3,5-dinitrob
enzene-sulfonamide], pendimethalin -ethylpropyl)-3,4-dimethyl-2,6-dini
trobenzamine]), and oxyfluorfen thoxy-4-nitrophenoxy)-4-(trifluorometh
yl)benzene], active ingredients in the granular formulations of Rout b
enzene+3,5-dinitro-N-4,N-4-dipropylsulfanilamide] and OH-2 (Ornamental
Herbicide-2), were evaluated. Herbicides were applied at labeled rate
s and followed by irrigation. Water samples were collected, herbicides
were extracted by solid phase extraction and analyzed by reverse phas
e high pressure liquid chromatography with ultraviolet (UV) detection.
Maximum herbicide residues were detected within the first 15 min of w
ater runoff; oryzalin residues were the greatest of the three herbicid
es evaluated (4 mg L(-1) water at 15 min) and showed rapid decreases t
hereafter. Herbicide residues detected in pond samples decreased over
time until the detection limit was reached (2 wk following application
). A microplot study was conducted to evaluate the effects of plastic,
woven fabric or gravel bedcovers on herbicide movement. Plastic and f
abric allowed greatest movement of oryzalin and pendimethalin, while g
ravel significantly retained and retarded movement of all three herbic
ides. Results indicate that bedcover composition plays a significant r
ole in the movement of herbicide from the site of application. Release
of active ingredient from granular formulations was evaluated; dinitr
oani-lines (oryzalin and pendimethalin) release faster than oxyfluorfe
n. Oryzalin in Rout was the most rapidly released, is the most water s
oluble, and 71% of total active ingredient was accounted for after 3 w
k.