MECHANICALLY ALLOYED NI50TI50 AND ITS TRANSFORMATION BY THERMAL TREATMENTS

Amorphous powders have been obtained by mechanical alloying (MA) equia tomic powder mixtures of nickel and titanium. The amorphous phase thus formed decomposes upon heating first into the cubic B2 NiTi intermeta llic compound; however, further heating promotes the precipitation of the intermetallics Ni3Ti and NiTi2. These transformations are shown to occur also in mechanically ground (MG) NiTi wire, but not in this sam e material exempted from ball-milling processing. It is suggested that this unique behaviour is brought about by the particular structural f eatures of the MA or MG powders, which promote the otherwise sluggish decomposition of B2 NiTi.