J. Jelitto et al., LAYER SILICATES FROM SERPENTINITE-PEGMATITE CONTACT (WIRY, LOWER SILESIA, POLAND), Clays and clay minerals, 41(6), 1993, pp. 693-701
Highly tectonized contact between serpentinite and younger pegmatite i
n the magnesite mine of Wiry contains various layer silicates. Vermicu
lite, chlorite, smectite, and interstratified mica-vermiculite were re
cognized by means of routine XRD examination. Two three component inte
rstratifications of mica-vermiculite-chlorite and chlorite-swelling ch
lorite-smectite were identified by a combined procedure of deconvoluti
on of the XRD patterns and simulation of XRD tracings. A mineral with
large diffraction maxima, displaying ''chlorite intergrade'' character
istics, appeared to be a mixture of chlorite, mixed layer chlorite-sme
ctite, and vermiculite. Polytypes of phyllosilicates were determined b
y the X-ray transmission method. Due to the heritage of parent mineral
polytype structure by transitional products of alteration, two distin
ct sequences of layer silicates were observed: one formed from triocta
hedral mica (vermiculite, mixed layer mica-vermiculite); and one evolv
ed from chlorite (e.g., mixed layer chlorite-swelling chlorite-smectit
e). A tentative scheme of the primary contact zone structure, not obsc
ured by subsequent brittle tectonics either by transformation of layer
silicates, is proposed.