CONSTRUCTION OF BASIS VIBRATION-SPECTRA OF MULTICOMPONENT SYSTEMS .3.AEROGEL

Citation
Iv. Markichev et al., CONSTRUCTION OF BASIS VIBRATION-SPECTRA OF MULTICOMPONENT SYSTEMS .3.AEROGEL, Journal of structural chemistry, 34(4), 1993, pp. 513-522
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Physical
ISSN journal
00224766
Volume
34
Issue
4
Year of publication
1993
Pages
513 - 522
Database
ISI
SICI code
0022-4766(1993)34:4<513:COBVOM>2.0.ZU;2-W
Abstract
Capillary-hollow silica (aerogel) is regarded as a three-component sys tem consisting of the silica core, the hydroxyl component, and absorbe d water. Its spectra of the doubly amplitude-weighted density of vibra tion states (AWDS), recorded at 10 K using the inelastic neutron scatt ering, were decomposed into the spectra of the components of the syste m. The study uses the difference correlation technique based on the po stulated lack of correlation between the basis spectra. The decomposit ion has been made by constructing physically significant basis spectra satisfying the criterion of zero coefficient of linear correlation, f or the starting and modified samples of aerogel AG200.