Iv. Markichev et al., CONSTRUCTION OF BASIS VIBRATION-SPECTRA OF MULTICOMPONENT SYSTEMS .3.AEROGEL, Journal of structural chemistry, 34(4), 1993, pp. 513-522
Capillary-hollow silica (aerogel) is regarded as a three-component sys
tem consisting of the silica core, the hydroxyl component, and absorbe
d water. Its spectra of the doubly amplitude-weighted density of vibra
tion states (AWDS), recorded at 10 K using the inelastic neutron scatt
ering, were decomposed into the spectra of the components of the syste
m. The study uses the difference correlation technique based on the po
stulated lack of correlation between the basis spectra. The decomposit
ion has been made by constructing physically significant basis spectra
satisfying the criterion of zero coefficient of linear correlation, f
or the starting and modified samples of aerogel AG200.