THE REACTION OF DIAZINES WITH ALLYLTRIBUTYLTIN VIA N-ALKOXYCARBONYLDIAZINIUM SALTS

Authors
ITOH T HASEGAWA H NAGATA K MATSUYA Y OHSAWA A
Citation
T. Itoh et al., THE REACTION OF DIAZINES WITH ALLYLTRIBUTYLTIN VIA N-ALKOXYCARBONYLDIAZINIUM SALTS, Heterocycles, 37(2), 1994, pp. 709-713
Citations number
8
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Heterocycles → ACNP
ISSN journal
03855414
Volume
37
Issue
2
Year of publication
1994
Pages
709 - 713
Database
ISI
SICI code
0385-5414(1994)37:2<709:TRODWA>2.0.ZU;2-M
Abstract
Pyridazines were allowed to react with allyltributyltin in the presenc e of chloroformate to give 1-alkoxycarbonyl-6-allyl- and 1-alkoxycarbo nyl-4-allyl-dihydro-pyridazines as major and minor products, respectiv ely. The reaction was applied to other diazines, and tetrahydro-adduct s were obtained in the case of pyrimidine and pyrazine. Benzo-fused di azines also reacted in the same manner to afford the allyl-adducts in good yields.