SYNTHESIS OF NOVEL HETEROCYCLIC CLEFTS DERIVED FROM TETRACYCLO[6.3.0.0(4,11).0(5,9)]UNDECANE-3,6-DIONE AND TRICYCLO-[6.3.0.0(2,6)]UNDECANE-3,11-DIONE

Authors
HADDADIN MJ WANG YJ FRENKEL S BOTT SG YANG L BRATERMAN PS CARVALLO C MARCHAND AP WATSON WH KASHYAP RP KRAWIEC M BOURNE SA
Citation
Mj. Haddadin et al., SYNTHESIS OF NOVEL HETEROCYCLIC CLEFTS DERIVED FROM TETRACYCLO[6.3.0.0(4,11).0(5,9)]UNDECANE-3,6-DIONE AND TRICYCLO-[6.3.0.0(2,6)]UNDECANE-3,11-DIONE, Heterocycles, 37(2), 1994, pp. 869-882
Citations number
26
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Heterocycles → ACNP
ISSN journal
03855414
Volume
37
Issue
2
Year of publication
1994
Pages
869 - 882
Database
ISI
SICI code
0385-5414(1994)37:2<869:SONHCD>2.0.ZU;2-D
Abstract
New molecular clefts (6a-6c), (9a), and (9b) have been prepared via ba se promoted reactions of 3,6-diaryl-1,2,4,5-tetrazines with tetracyclo [6.3.0.0(4,11).0(5,9)]undecane-3,6-dione (1) and with tricyclo[6.3.0.0 (2,6)]undecane-3,11-dione (10), respectively. Compounds of this type a re of interest as a potential new class of host molecules for use in h ost-guest complexation studies (i.e., inclusion phenomena and molecula r recognition). The results obtained via studies of the solution elect rochemistry of systems (6a-6c), (9a), and (9b) afforded no evidence fo r the existence of any significant electronic interaction between oppo sing ''arms'' in these molecular clefts.