ZIRCONIUM DIAZABUTADIENE COMPLEXES OF THE TYPE ZR(DAD)3

Authors
THIELE KH RICHTER B
Citation
Kh. Thiele et B. Richter, ZIRCONIUM DIAZABUTADIENE COMPLEXES OF THE TYPE ZR(DAD)3, Zeitschrift fur anorganische und allgemeine Chemie, 620(3), 1994, pp. 519-522
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
620
Issue
3
Year of publication
1994
Pages
519 - 522
Database
ISI
SICI code
0044-2313(1994)620:3<519:ZDCOTT>2.0.ZU;2-E
Abstract
1,4-Diazabutadienes (DAD), RN = CPh-CPh = NR 1 (R = C6H5 a, CH3C6H4 b, CH3OC6H4 c), react with ZrCl4 . 2THF with formation of complexes of t he type ZrCl4 . DAD 2. At interaction with lithium diazadienides Li2DA D deep coloured complexes of the composition Zr(DAD)3 3 are formed. Th e new compounds were characterized by elemental analysis, i.r., H-1- a nd C-13-n.m.r. spectra.