Pp. Singh et al., SOLUTE-SOLUTE INTERACTION ENTHALPIES IN SOLUTIONS OF COPPER(II) CHLORIDE IN ORGANIC-SOLVENTS HAVING NITROGEN DONOR ATOMS, Fluid phase equilibria, 93, 1994, pp. 277-283
The dissolution behaviour of anhydrous cupric chloride (i) in solvents
having a nitrogen donor atom (S) such as aniline, o-toluidine, pyridi
ne, formamide and N,N-dimethyl-formamide, has been studied at 298.15 K
by determining molar enthalpies of dilution of S(i) (a solvent S satu
rated with i). The data, when analysed in terms of the Mayer-McMillan
approach, yielded binary (h(ii)) and ternary (h(iii)) interactional en
ergy parameters of i in these solvents and have been utilized to expla
in the different extent of solubility of CuCl2 in the above-mentioned
solvents. The analysis of the h(ii) data has further suggested that h(
ii) and h(iii) should necessarily vary in opposite directions.