A NEW ACTIVE CATALYST SPECIES FOR ENANTIOSELECTIVE ALKYLATION BY PHASE-TRANSFER CATALYSIS

Authors
ODONNELL MJ WU SD HUFFMAN JC
Citation
Mj. Odonnell et al., A NEW ACTIVE CATALYST SPECIES FOR ENANTIOSELECTIVE ALKYLATION BY PHASE-TRANSFER CATALYSIS, Tetrahedron, 50(15), 1994, pp. 4507-4518
Citations number
77
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
50
Issue
15
Year of publication
1994
Pages
4507 - 4518
Database
ISI
SICI code
0040-4020(1994)50:15<4507:ANACSF>2.0.ZU;2-Z
Abstract
This paper briefly reviews the use of Schiff base substrates in amino acid synthesis. Recent studies lead to the proposal of a new active ca talyst species (12) for the asymmetric PTC alkylation of active methyl ene compounds (2). Mechanistic implications are detailed.