Jy. Carriat et al., INFLUENCE OF ORDER-DISORDER PARAMETERS ON THE REDUCIBILITY OF NI-CONTAINING AND CU-CONTAINING SILICATES - APPLICATION TO TALC AND CHRYSOCOLLA, Catalysis letters, 25(1-2), 1994, pp. 127-140
Reference phyllosilicates (Ni-talcs and chrysocolla) have been synthes
ized with the aim of identifying supported layered silicates in the pr
eparation of Ni/SiO2 and Cu/SiO2 materials. The analysis of temperatur
e programmed reduction (TPR) profiles and X-ray diffraction (XRD) patt
erns of talc synthesized at different temperatures shows a strong infl
uence of the crystallinity of the Ni silicate on its reducibility. Chr
ysocolla remains ill-crystallized whatever the temperature of synthesi
s. The reducibility of the two silicates is discussed in terms of the
structure of the silicate and the reducibility of the transition metal
-ion. The asymmetric shape of the TPR curves of Ni-talcs is interprete
d on the basis of the phase-boundary controlled model and the presence
of a heterogeneous particle size distribution. The results emphasize
the role of the crystallinity and show that the identification of supp
orted silicate phases from TPR only may not be reliable.