H. Miyazaki et al., IMPROVED PHOSPHOSILICATE GLASS PASSIVATION AGAINST CU CONTAMINATION USING THE RAPID THERMAL ANNEALING PROCESS, Journal of the Electrochemical Society, 141(3), 1994, pp. 734-736
Passivation against Cu contamination is a key technology for realizing
multilevel Cu interconnection for ultralarge scale integrated circuit
s (ULSI). Phosphosilicate glass (PSG) with rapid thermal annealing (RT
A) is found to provide no less of a passivation effect than furnace-an
nealed (FA) PSG films, while significantly reducing the thermal budget
of the PSG annealing from 900-degrees-C x 20 min (FA) to 900-degrees-
C X 60 s (RTA). This suggests that the PSG-RTA process is applicable t
o 0.25 mum level metal oxide semiconductor (MOS) ULSIs, since both the
amount of Cu diffusion and the thermal budget are within the limits o
f 0.25 mum MOS device technology.