REACTIONS OF P-PHENYL C-AMINO ALKYLIDENEP HOSPHINES WITH DIAZO-COMPOUNDS

Citation
M. Rahmouni et al., REACTIONS OF P-PHENYL C-AMINO ALKYLIDENEP HOSPHINES WITH DIAZO-COMPOUNDS, Bulletin des Societes chimiques belges, 102(11-12), 1993, pp. 719-728
Citations number
29
Categorie Soggetti
Chemistry
ISSN journal
00379646
Volume
102
Issue
11-12
Year of publication
1993
Pages
719 - 728
Database
ISI
SICI code
0037-9646(1993)102:11-12<719:ROPCAH>2.0.ZU;2-5
Abstract
P-Phenyl C-aminophosphaalkenes 1 react with some disubstituted diazoco mpounds at -20-degrees-C leading to tricoordinated phosphorus compound s 2, 9. 11 and 12 via a Staudinger type reaction. These compounds deco mpose already at room temperature and quickly by heating. Azines are i solated after extrusion of phenyl phosphinidene.