METHYL HENYL]METHYL)-5-OXO-2,5-DIHYDROFURAN-2-CARBOXYLATE

Citation
Tr. Boehlow et al., METHYL HENYL]METHYL)-5-OXO-2,5-DIHYDROFURAN-2-CARBOXYLATE, Acta crystallographica. Section C, Crystal structure communications, 53, 1997, pp. 92-95
Citations number
6
Categorie Soggetti
Crystallography
ISSN journal
01082701
Volume
53
Year of publication
1997
Part
1
Pages
92 - 95
Database
ISI
SICI code
0108-2701(1997)53:<92:MH>2.0.ZU;2-T
Abstract
The title compound, C25H28O11, is formed by a homoaldol condensation o f methyl [4-methoxy-2-(methoxymethylenoxy)phenyl]pyruvate followed by lactonization, The structure consists of a butenolide ring substituted at the 2 position by an arylmethyl and a methyl carboxylate group, at the 3 position by an aryl group and at the 2 position by a hydroxyl g roup. The solid-state structure contains a hydrogen-bonded cyclic dime r. The hydrogen bonds are formed between the enol H atom of one molecu le and the lactone carbonyl O atom of another.