THE STABILITY-CONSTANTS OF SILVER-IODIDE COMPLEXES IN DMF

Authors
GAIZER F SIPOS P LAZAR J
Citation
F. Gaizer et al., THE STABILITY-CONSTANTS OF SILVER-IODIDE COMPLEXES IN DMF, Polyhedron, 13(5), 1994, pp. 855-857
Citations number
8
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
13
Issue
5
Year of publication
1994
Pages
855 - 857
Database
ISI
SICI code
0277-5387(1994)13:5<855:TSOSCI>2.0.ZU;2-E
Abstract
The interaction of silver and iodide ions in N,N-dimethylformamide (DM F) at 25-degrees-C has been investigated by potentiometric measurement s over 5-50 mM concentration range. The stability constants of the com plexes AgI, Ag6I82-, Ag5I72-, Ag4I52-, Ag2I42-, AgI2- and AgI32- have been determined by systematic computer evaluation of the results. The stability constants of the corresponding complexes are larger in DMF t han in DMSO.