FACTORIZATION OF LIGAND-BASED REDUCTION POTENTIALS

Authors
DODSWORTH ES VLCEK AA LEVER ABP
Citation
Es. Dodsworth et al., FACTORIZATION OF LIGAND-BASED REDUCTION POTENTIALS, Inorganic chemistry, 33(6), 1994, pp. 1045-1049
Citations number
39
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
33
Issue
6
Year of publication
1994
Pages
1045 - 1049
Database
ISI
SICI code
0020-1669(1994)33:6<1045:FOLRP>2.0.ZU;2-0
Abstract
The reduction potentials of a series of polypyridine complexes of Mo0, Os(II), Re(I), and Ru(II), some nitrosyl Os(II) and Ru(II) complexes, and a series of dinitrosylmolybdenum species are parametrized with th e SIGMAE(L)(L) parameter. The slope, S(L), and intercept, I(L), of the linear correlations are shown to relate to metal-ligand coupling and interligand coupling through the metal center.