New highly concentrated emulsions have been made from fluorocarbons an
d nonionic fluorinated surfactants. They can contain till 98 % water a
s the dispersed phase. With such a water content, they are viscoelasti
c materials like gels. They are optically transparent, an original pro
perty for emulsion systems. The continuous phase is water swollen mice
llar phase. Their structure has been studied by small angle X-ray and
neutron scattering, and correlated to rheological properties and stabi
lity (phase diagrams). The parameters of interest are the chemical str
ucture of the surfactants, the composition, temperature and water sali
nity.