THE PHOTOCHEMISTRY OF ACETYLENIC ETHERS - A NOVEL CARBON-OXYGEN TOE CARBON-CARBON BOND CONVERSION

Authors
SMITH BA CALLINAN AJ SWENTON JS
Citation
Ba. Smith et al., THE PHOTOCHEMISTRY OF ACETYLENIC ETHERS - A NOVEL CARBON-OXYGEN TOE CARBON-CARBON BOND CONVERSION, Tetrahedron letters, 35(15), 1994, pp. 2283-2286
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
15
Year of publication
1994
Pages
2283 - 2286
Database
ISI
SICI code
0040-4039(1994)35:15<2283:TPOAE->2.0.ZU;2-5
Abstract
Irradiation of acetylenic ethers in methanol gives homologated esters via a formal 1,3-oxygen-to-carbon migration involving a ketene inter mediate.