HIGHLY REGIOSELECTIVE PALLADIUM-MEDIATED SUBSTITUTION OF ALLYLIC AND DIENYLIC CYCLIC CARBONATES

Authors
KANG SK PARK DC JEON JH RHO HS YU CM
Citation
Sk. Kang et al., HIGHLY REGIOSELECTIVE PALLADIUM-MEDIATED SUBSTITUTION OF ALLYLIC AND DIENYLIC CYCLIC CARBONATES, Tetrahedron letters, 35(15), 1994, pp. 2357-2360
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
15
Year of publication
1994
Pages
2357 - 2360
Database
ISI
SICI code
0040-4039(1994)35:15<2357:HRPSOA>2.0.ZU;2-S
Abstract
Reaction of chiral allylic and dienylic cyclic carbonates with various nucleophiles in the presence of (PPh(3))(4)Pd as a catalyst afforded alpha-, gamma-, or epsilon-substituted products with high regio-, (E)- stereo-, and diastereoselectivity depending on nucleophiles.