SYNTHESIS OF ACETALS FROM ALKENES BY ONE-POT HYDROFORMYLATION-TRANSACETALIZATION REACTIONS CATALYZED BY RHODIUM COMPLEXES AND PYRIDINIUM P-TOLUENESULPHONATE
E. Fernandez et S. Castillon, SYNTHESIS OF ACETALS FROM ALKENES BY ONE-POT HYDROFORMYLATION-TRANSACETALIZATION REACTIONS CATALYZED BY RHODIUM COMPLEXES AND PYRIDINIUM P-TOLUENESULPHONATE, Tetrahedron letters, 35(15), 1994, pp. 2361-2364
Efficient conversion of alkenes to acetals has been achieved by consec
utive hydroformylation-acetalization reactions catalyzed by rhodium co
mplexes and pyridinium p-toluenesulphonate or by a zwitterionic rhodiu
m catalyst.