ANOMALOUS ROLE OF MOLECULAR-SIEVES 4A IN THE PREPARATION OF A BINAPHTHOL-DERIVED ACTIVE MU(3)-OXO TITANIUM CATALYST

Authors
TERADA M MATSUMOTO Y NAKAMURA Y MIKAMI K
Citation
M. Terada et al., ANOMALOUS ROLE OF MOLECULAR-SIEVES 4A IN THE PREPARATION OF A BINAPHTHOL-DERIVED ACTIVE MU(3)-OXO TITANIUM CATALYST, Chemical communications, (3), 1997, pp. 281-282
Citations number
25
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
3
Year of publication
1997
Pages
281 - 282
Database
ISI
SICI code
1359-7345(1997):3<281:AROM4I>2.0.ZU;2-P
Abstract
The active species of binaphthol-derived titanium catalyst 1, which is used as an efficient: catalyst for glyoxylate-ene reactions, is prima rily composed of a mu(3)-oxo (Ti3O) species, for which the molecular s ieves 4A employed in the catalyst preparation act as a H2O donor.