SYNTHESIS, CRYSTAL-STRUCTURE AND REARRANGEMENT OF A METHYLENE(YLENE)PHOSPHORANE CONTAINING A CH2-MOIETY AT AN SP(2)-HYBRIDIZED PHOSPHORUS(V) CENTER

Authors
SCHINKELS B RUBAN A NIEGER M NIECKE E
Citation
B. Schinkels et al., SYNTHESIS, CRYSTAL-STRUCTURE AND REARRANGEMENT OF A METHYLENE(YLENE)PHOSPHORANE CONTAINING A CH2-MOIETY AT AN SP(2)-HYBRIDIZED PHOSPHORUS(V) CENTER, Chemical communications, (3), 1997, pp. 293-294
Citations number
14
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
3
Year of publication
1997
Pages
293 - 294
Database
ISI
SICI code
1359-7345(1997):3<293:SCAROA>2.0.ZU;2-D
Abstract
The reaction of the iminophosphane, (Me(3)Si)(3)C-P=N-Mes, with Me(2) S=CH2 affords the first methylenephosphorane containing a CH2 moiety a t an sp(2)-hybridized phosphorus(v) centre; the crystal structure as w ell the rearrangement of which is reported.