T. Asano et al., SINGLE-CRYSTAL SUSCEPTIBILITY OF THE S=1 ONE-DIMENSIONAL HEISENBERG-ANTIFERROMAGNET AGVP2S6, Solid state communications, 90(2), 1994, pp. 125-128
A reliable single crystal susceptibility data is reported to reveal th
e ground state property of the S = 1 one-dimensional Heisenberg antife
rromagnet AgVP2S6. The observed susceptibilities for the parallel and
perpendicular direction to the chain axis fall down rapidly as the tem
perature is lowered down to about 50 K, revealing a non-magnetic singl
et ground state nature of the system. The results are interpreted quan
titatively within the framework of the Haldane prediction, giving the
quantum gap of E(g)/k(B) almost-equal-to 250 K which should be compare
d with 320 K from neutron scattering.