THE PLASMA EMISSION DETECTOR (PED) AS AN ELEMENT-SELECTIVE DETECTOR FOR SUPERCRITICAL-FLUID CHROMATOGRAPHY

Citation
M. Arnold et al., THE PLASMA EMISSION DETECTOR (PED) AS AN ELEMENT-SELECTIVE DETECTOR FOR SUPERCRITICAL-FLUID CHROMATOGRAPHY, Fresenius' journal of analytical chemistry, 348(8-9), 1994, pp. 546-548
Citations number
3
Categorie Soggetti
Chemistry Analytical
ISSN journal
09370633
Volume
348
Issue
8-9
Year of publication
1994
Pages
546 - 548
Database
ISI
SICI code
0937-0633(1994)348:8-9<546:TPED(A>2.0.ZU;2-J
Abstract
The plasma emission detector (PED) has been shown to be an element spe cific detector for supercritical fluid chromatography (SFC). The commo nly used eluents (CO2 and N2O) tend to disturb the He plasma; two diff erent discharge tubes were tested in an attempt to overcome this probl em. Promising results were obtained with a concentric dual flow torch design for the element specific detection of Cl, H, and C containing a nalytes using N2O as SFC mobile phase.