YIELD OF (OSO)-O-16-O-18 FROM THE (OH)-O-18 INITIATED OXIDATION OF CS2 IN O-16(2)

Authors
LOVEJOY ER RAVISHANKARA AR HOWARD CJ
Citation
Er. Lovejoy et al., YIELD OF (OSO)-O-16-O-18 FROM THE (OH)-O-18 INITIATED OXIDATION OF CS2 IN O-16(2), International journal of chemical kinetics, 26(5), 1994, pp. 551-560
Citations number
19
Categorie Soggetti
Chemistry Physical
Journal title
International journal of chemical kinetics → ACNP
ISSN journal
05388066
Volume
26
Issue
5
Year of publication
1994
Pages
551 - 560
Database
ISI
SICI code
0538-8066(1994)26:5<551:YO(FT(>2.0.ZU;2-8
Abstract
The yield of (OSO)-O-16-O-18 from the (0H)-O-18 initiated oxidation of CS2 in O-16(2) was measured by using a discharge flow reactor coupled to a chemical ionization mass spectrometer. (OSO)-O-16-O-18 is the do minant SO2 isotopomer produced with a yield of 0.90 +/- 0.20 relative to (OH)-O-18 loss. The errors are estimates for the uncertainty at the 95% confidence level. The implications of these results to the unders tanding of the CS2 oxidation mechanism are discussed. (C) 1994 John Wi ley & Sons, Inc.*