Er. Lovejoy et al., YIELD OF (OSO)-O-16-O-18 FROM THE (OH)-O-18 INITIATED OXIDATION OF CS2 IN O-16(2), International journal of chemical kinetics, 26(5), 1994, pp. 551-560
The yield of (OSO)-O-16-O-18 from the (0H)-O-18 initiated oxidation of
CS2 in O-16(2) was measured by using a discharge flow reactor coupled
to a chemical ionization mass spectrometer. (OSO)-O-16-O-18 is the do
minant SO2 isotopomer produced with a yield of 0.90 +/- 0.20 relative
to (OH)-O-18 loss. The errors are estimates for the uncertainty at the
95% confidence level. The implications of these results to the unders
tanding of the CS2 oxidation mechanism are discussed. (C) 1994 John Wi
ley & Sons, Inc.*