J. Rocek et P. Uchytil, EVALUATION OF SELECTED METHODS FOR THE CHARACTERIZATION OF CERAMIC MEMBRANES, Journal of membrane science, 89(1-2), 1994, pp. 119-129
Defect-free surface layers with narrow pore size distributions and opt
imal porosity of support and supporting layers are desirable propertie
s of ceramic membranes. When fouling, concentration polarisation and i
nteractions of molecules with pore walls are negligible, the permeabil
ity in ceramic membranes and the efficiency of the separation process
are determined mainly by the membrane pore structure. That is why the
porous structure of ceramic membranes must be reliably tested. Ceramic
membranes are often tested by mercury porosimetry. Other suitable met
hods - Coulter porosimetry and permeation - are relative new. A compar
ison of the possibilities and limitations of these methods and an expl
anation of the differences in the obtained results are discussed. Prob
lems connected with the preparation of membrane samples for measuremen
t are also embraced.