ZEOLITE-FILLED SILICONE-RUBBER MEMBRANES EXPERIMENTAL-DETERMINATION OF CONCENTRATION PROFILES

Citation
Hjct. Hennepe et al., ZEOLITE-FILLED SILICONE-RUBBER MEMBRANES EXPERIMENTAL-DETERMINATION OF CONCENTRATION PROFILES, Journal of membrane science, 89(1-2), 1994, pp. 185-196
Citations number
18
Categorie Soggetti
Engineering, Chemical","Polymer Sciences
Journal title
ISSN journal
03767388
Volume
89
Issue
1-2
Year of publication
1994
Pages
185 - 196
Database
ISI
SICI code
0376-7388(1994)89:1-2<185:ZSMEO>2.0.ZU;2-U
Abstract
Permeant concentrations in silicalite-filled silicone rubber membranes during pervaporation of propanol/water mixtures were measured using m ulti-layered membranes. Experimentally determined concentration profil es show that the propanol concentration in the silicalite-filled membr ane increases with increasing silicalite content. The water concentrat ion in the membrane is low and no water is present in the silicalite p articles during pervaporation. The concentration profiles measured her e support the observations from the resistance model that the diffusio n through the membrane determines the transport rate, i.e., adsorption is a fast process.