W. Bohme et al., OBSERVATION OF DUST PARTICLE GROWTH AND FALLOUT IN RF-EXCITED SILANE DISCHARGES, IEEE transactions on plasma science, 22(2), 1994, pp. 110-115
Particles formed during plasma enhanced chemical vapor deposition of a
morphous silicon thin films which fall to the film surface, either dur
ing or after the process, may have a severely deleterious effect on fi
lm properties. In order to understand the mechanisms of particle forma
tion and fallout we have investigated the growth and dynamics of parti
cles in RF discharges in pure silane. The diameter of particles formed
within the first 20 s of the discharge was investigated by electron m
icroscopy of substrates with fallen out particles. Furthermore we used
a He-Ne laser in combination with a diode array camera to measure tem
porally and spatially resolved light scattering from particles and ded
uced their sinking speed after switching off the discharge. The result
s are compared to a theoretical model on the particle dynamics.