Four tinplate specimens with different corrosion properties were studi
ed using secondary ion mass spectrometry (SIMS) image analysis. The co
ntinuity of the structure of the interfacial iron-tin alloy was able t
o be examined using a volume rendition computer program, which generat
es a three-dimensional representation of the stack of ion images. The
surface coverage of tinplate was found to vary widely on some specimen
s; those exhibiting poor corrosion characteristics were found to have
little or no elemental tin covering the raised regions between the rol
ling grooves