R. Imdahl et al., SPECTROSCOPIC AND X-RAY STRUCTURAL INVEST IGATIONS ON DICHLOROMETHYL MERCURY-COMPOUNDS, Zeitschrift fur anorganische und allgemeine Chemie, 620(4), 1994, pp. 625-631
Citations number
32
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
Bis(dichloromethyl)mercury, Hg(CHCl2)2, and mixed alkyl compounds RHgC
HCl2 (with R = CH3, C2H5) have been synthesized by known methods from
CH2Cl2, lithium butanide and HgCl2, CH3HgCl or C2H5HgCl, respectively.
The H-1-, C-13-NMR as well as the IR and Raman spectra of the liquid
alkyls RHgCHCl2 and the high melting Hg(CHCl2)2 have been measured and
assigned. According to the X-ray structure determination Hg(CHCl2)2 c
rystallizes in the monoclinic space group P2(1)/c with 4 non-symmetric
molecules per unit cell (R = 0.046).