PREPARATION OF MU-SULFURDISULFONIUM SALTS [(CH3)2S-S(X)-S(CH3)2]2- (X=1-3, A-=ASF6-, SBF6-, SBCL6-) - ON THE ANALOGY OF THE REACTIVITY OF SULFANES AND SULFONIUM SALTS(2A)

Authors
MINKWITZ R KORNATH A KRAUSE R PREUT H
Citation
R. Minkwitz et al., PREPARATION OF MU-SULFURDISULFONIUM SALTS [(CH3)2S-S(X)-S(CH3)2]2- (X=1-3, A-=ASF6-, SBF6-, SBCL6-) - ON THE ANALOGY OF THE REACTIVITY OF SULFANES AND SULFONIUM SALTS(2A), Zeitschrift fur anorganische und allgemeine Chemie, 620(4), 1994, pp. 632-637
Citations number
33
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
620
Issue
4
Year of publication
1994
Pages
632 - 637
Database
ISI
SICI code
0044-2313(1994)620:4<632:POMS[(>2.0.ZU;2-D
Abstract
The preparation of the mu-sulfurdisulfonium salts [(CH3)2S-Sx-S(CH3)2] 2+(A-)2 with x = 1-3 and A- = AsF6-, SbF6-, SbCl6- is reported. The sa lts are formed by reaction of (CH3)2SH+A- and (CH3)2SSH+A- with SCl2 a nd S2Cl2, resp.. They are characterized by vibrational spectroscopic m easurements. [(CH3)2S-S2-S(CH3)2]2+(SbF6-)2 crystallizes in the space group C2/c with a = 1 884.5(7) pm, b = 1 302.8(5) pm, c = 1 477.2(5) p m, beta = 98.62(3)degrees und Z = 8.