CONTRIBUTIONS TO THE CHEMISTRY OF TRANSIT ION-METAL ALKYL-COMPOUNDS .62. PREPARATION AND NMR-SPECTROSCOPIC CHARACTERIZATION OF TETRAMETHYLTITANIUM COMPLEXES

Authors
THIELE KH WINDISCH H BOGEL H DETTMANN J
Citation
Kh. Thiele et al., CONTRIBUTIONS TO THE CHEMISTRY OF TRANSIT ION-METAL ALKYL-COMPOUNDS .62. PREPARATION AND NMR-SPECTROSCOPIC CHARACTERIZATION OF TETRAMETHYLTITANIUM COMPLEXES, Zeitschrift fur anorganische und allgemeine Chemie, 620(4), 1994, pp. 697-702
Citations number
26
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
620
Issue
4
Year of publication
1994
Pages
697 - 702
Database
ISI
SICI code
0044-2313(1994)620:4<697:CTTCOT>2.0.ZU;2-Q
Abstract
Complexes of tetramethyltitanium with THF and oxygen, nitrogen and pho sphorous containing chelating ligands were synthesized and characteriz ed by low temperature n.m.r. spectroscopy. The obtained complexes show a dynamic behaviour in solutions. The results of semiempirical MO cal culations favour octahedral and not a trigonal prismatic configuration of the complexes.