SYNTHESES AND STRUCTURES OF FUNCTIONAL SU BSTITUTED FERROCENES

Authors
GRUNHAGEN A PIEPER U KOTTKE T ROESKY HW
Citation
A. Grunhagen et al., SYNTHESES AND STRUCTURES OF FUNCTIONAL SU BSTITUTED FERROCENES, Zeitschrift fur anorganische und allgemeine Chemie, 620(4), 1994, pp. 716-722
Citations number
53
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
620
Issue
4
Year of publication
1994
Pages
716 - 722
Database
ISI
SICI code
0044-2313(1994)620:4<716:SASOFS>2.0.ZU;2-V
Abstract
Substituted ferrocenes have been prepared using carbonic acid chloride of ferrocene. New pathways have been found reacting the acid chloride with sodium hexamethyldisilazane and tris(trimethylsilyl)phosphane, r espectively. The compounds FecC(OSiMe3)N(SiMe3) (Fec = C5H5FeC5H4) 1 a nd FecC(OSiMe3)P(SiMe3) 2 have been obtained and characterized by X-ra y single crystal structure analysis. Experiments for the preparation o f FecCP 3 are reported.