ON THE PREPARATION OF PNIKOGENONIUM SALTS ASH4-, ASH4+ASF6-, SBH4+SBF6-(SBF6)

Authors
MINKWITZ R KORNATH A SAWODNY W HARTNER H
Citation
R. Minkwitz et al., ON THE PREPARATION OF PNIKOGENONIUM SALTS ASH4-, ASH4+ASF6-, SBH4+SBF6-(SBF6), Zeitschrift fur anorganische und allgemeine Chemie, 620(4), 1994, pp. 753-756
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
620
Issue
4
Year of publication
1994
Pages
753 - 756
Database
ISI
SICI code
0044-2313(1994)620:4<753:OTPOPS>2.0.ZU;2-#
Abstract
The preparation of the pnikogenonium salts AsH4+SbF6-, AsH4+AsF6- and SbH4+SbF6- by protonation from the hydrides AsH3, SbH3 in superacidic systems HF/SbF5 and HF/AsF5, resp. is reported. The salts are characte rized by vibrational and mass spectra. A general valence force field i s calculated. The following onium ions are know as hexafluoroantimonat e: [GRAPHICS].