PHYSICAL AND ELECTRICAL CHARACTERISTICS OF THIN SILICON-NITRIDE DIELECTRIC FILMS DEPOSITED ON SMOOTH AND RUGGED POLYCRYSTALLINE SILICON AFTER RAPID THERMAL NITRIDATION
Vk. Mathews et al., PHYSICAL AND ELECTRICAL CHARACTERISTICS OF THIN SILICON-NITRIDE DIELECTRIC FILMS DEPOSITED ON SMOOTH AND RUGGED POLYCRYSTALLINE SILICON AFTER RAPID THERMAL NITRIDATION, Journal of the Electrochemical Society, 141(4), 1994, pp. 1066-1070
Rapid thermal nitridation (RTN) of the polycrystalline silicon (polysi
licon) storage node prior to the deposition of the silicon nitride die
lectric film has been investigated for capacitors with smooth and rugg
ed electrodes. The nitridation process modifies the bonding arrangemen
t on the polysilicon surface and leads to an enhancement of the nuclea
tion and growth characteristics of the subsequent silicon nitride depo
sition process. This results in the growth of a thicker film on the RT
N-treated surface for a given deposition time. For the same capacitanc
e, the addition of the nitridation treatment reduces the leakage curre
nt through silicon nitride films deposited on smooth polysilicon while
no such change in the leakage characteristics is seen for the rugged
polysilicon film. However, for both smooth and rugged polysilicon elec
trodes, there is an improvement in the breakdown distribution as well
as the time-dependent dielectric breakdown of the films with the nitri
dation process.