COMPARISON OF COMPLEXATION IN PR(NO3)3 AND PR(SCN)3 SOLUTIONS

Authors
MAJDAN M SADOWSKI P
Citation
M. Majdan et P. Sadowski, COMPARISON OF COMPLEXATION IN PR(NO3)3 AND PR(SCN)3 SOLUTIONS, Monatshefte fuer Chemie, 125(3), 1994, pp. 285-291
Citations number
17
Categorie Soggetti
Chemistry
Journal title
Monatshefte fuer Chemie → ACNP
ISSN journal
00269247
Volume
125
Issue
3
Year of publication
1994
Pages
285 - 291
Database
ISI
SICI code
0026-9247(1994)125:3<285:COCIPA>2.0.ZU;2-H
Abstract
The UV-Vis spectral data for Pr(SCN), NaSCN and Pr(NO3)3 LiNO3 are rep orted for 17, 25, 35, 50, and 61.3-degrees-C. The calculated absolute values of the stability constants for the Pr nitrato complexes are hig her than those for thiocyanates. The equilibria in outer vs. inner sph ere complexation in the system are discussed,