High quality CaF2/Si/CaF2/Si(111) structures have been grown epitaxial
ly by molecular beam epitaxy and characterized by X-ray diffraction an
alysis, Rutherford backscattering spectroscopy and transmission electr
on microscopy. High crystalline quality CaF2 layers are achieved when
the thickness of the middle Si layer is small. The films degrade if th
e thickness of the Si layer exceeds 10 nm. The epitaxial orientations
of the two CaF2 layers can be identical or azimuthally rotated 180 deg
rees with respect to each other, depending on how the middle Si film i
s deposited.