Vv. Kresin et al., VAN-DER-WAALS INTERACTION OF FINITE METALLIC SYSTEMS - A STUDY OF CLUSTER-ATOM SCATTERING, Physical review. A, 49(4), 1994, pp. 2696-2701
Absolute integral cross sections for elastic collisions of neutral sod
ium clusters Na(n) (n = 2-20) with sodium atoms have been measured and
the van der Waals interaction constants determined. The center-of-mas
s cross sections are very large (up to thousands of square angstroms),
reflecting high cluster polarizabilities. It is found that the disper
sion theory based on measured response parameters of alkali-metal clus
ters tends to overestimate the interaction strength.