F. Demichelis et al., OPTIMIZATION OF A-SI1-XCXH FILMS PREPARED BY ULTRAHIGH-VACUUM PLASMA-ENHANCED CHEMICAL-VAPOR-DEPOSITION FOR ELECTROLUMINESCENT DEVICES, Thin solid films, 241(1-2), 1994, pp. 274-277
The correlation between the deposition conditions and the structural a
nd optoelectronic properties of a-SiC:H were studied in order to obtai
n optimized device-quality films. Two different sets of films were dep
osited by plasma enhanced chemical vapour deposition, with and without
H-2 dilution of the mixture of SiH4 + CH4 respectively. An improvemen
t in the optoelectronic properties was observed: the H-2-diluted films
show higher photoconductivity, sharper Urbach energy, reduced sub-ban
d gap absorption and reduced CH(n) and SiH2 bond density with respect
to undiluted films. The growth mechanisms were interpreted by means of
chemical bonding configurations deduced from IR absorptance measureme
nts.