A NOVEL STEREOSELECTIVE SYNTHESIS OF (Z)-3-IODO-3-ALKEN-1-ONE FROM 2-ALKYN-1-ONE

Authors
LUO FT KUMAR KA HSIEH LC WANG RT
Citation
Ft. Luo et al., A NOVEL STEREOSELECTIVE SYNTHESIS OF (Z)-3-IODO-3-ALKEN-1-ONE FROM 2-ALKYN-1-ONE, Tetrahedron letters, 35(16), 1994, pp. 2553-2554
Citations number
4
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
16
Year of publication
1994
Pages
2553 - 2554
Database
ISI
SICI code
0040-4039(1994)35:16<2553:ANSSO(>2.0.ZU;2-2
Abstract
A one-pot reaction of 2-alkyn-1-one with sodium iodide/acetonitrile/tt imethylsilyl chloride/water or trimethylsilyl iodide/acetonitrile at 2 5 degrees C gave almost exclusively (Z)-3-iodo-3-alken-1-one in good y ields.