R. Antonioletti et al., BR-INDUCED CYCLIZATION OF GAMMA,DELTA-UNSATURATED KETONES - A NEW APPROACH TO BROMOPYRANE DERIVATIVES(), Tetrahedron letters, 35(16), 1994, pp. 2619-2620
3,5-dibromo-3,4-dihydro-2,2-dimethyl-(2H)-pyrans 2, are obtained throu
gh a simple and new procedure involving a bromoenol-etherification of
gamma,delta-unsaturated ketones 1; the key step is the formation of mo
no-bromopyran intermediate A.