ULTRAFAST RELAXATION OF THE FUNDAMENTAL VIBRATIONS OF SH- AND OH- IN POTASSIUM HALIDES

Citation
Ce. Mungan et al., ULTRAFAST RELAXATION OF THE FUNDAMENTAL VIBRATIONS OF SH- AND OH- IN POTASSIUM HALIDES, Journal of luminescence, 58(1-6), 1994, pp. 33-36
Citations number
7
Categorie Soggetti
Optics
Journal title
ISSN journal
00222313
Volume
58
Issue
1-6
Year of publication
1994
Pages
33 - 36
Database
ISI
SICI code
0022-2313(1994)58:1-6<33:UROTFV>2.0.ZU;2-7
Abstract
The vibrational relaxation times of SH- and OH- in potassium halides, measured by incoherent laser saturation, vary from 0.8 to 7 ns at 1.7 K. A librational side band at +300 cm-1 provides a possible decay chan nel. The strength of this mode is strongly temperature dependent, poss ibly owing to barrier hopping.