A new Si cluster material, tertiary-butyloctasilacubane (tBuSi)8, is u
sed as an efficient Si doping source for molecular beam epitaxy of GaA
s. The vapor pressure of this material varies according to an activati
on energy of 1.51 eV. A Si concentration of 2 x 10(20) /cm3 is obtaine
d at a Si cluster cell temperature of 210-degrees-C and a GaAs growth
rate of 1 mum/h. Although the grown layers suffer from heavy carbon co
ntamination from the Si cluster, this problem can be alleviated by inc
reasing the substrate temperature.