DENSITIES, REFRACTIVE-INDEXES, SPEEDS OF SOUND, AND SHEAR VISCOSITIESOF DIETHYLENE GLYCOL DIMETHYL ETHER WITH ETHYL-ACETATE, METHYL BENZOATE, ETHYL BENZOATE, AND DIETHYL SUCCINATE IN THE TEMPERATURE-RANGE FROM 298.15 TO 318.15-K

Citation
Tm. Aminabhavi et al., DENSITIES, REFRACTIVE-INDEXES, SPEEDS OF SOUND, AND SHEAR VISCOSITIESOF DIETHYLENE GLYCOL DIMETHYL ETHER WITH ETHYL-ACETATE, METHYL BENZOATE, ETHYL BENZOATE, AND DIETHYL SUCCINATE IN THE TEMPERATURE-RANGE FROM 298.15 TO 318.15-K, Journal of chemical and engineering data, 39(2), 1994, pp. 251-260
Citations number
36
Categorie Soggetti
Engineering, Chemical",Chemistry
ISSN journal
00219568
Volume
39
Issue
2
Year of publication
1994
Pages
251 - 260
Database
ISI
SICI code
0021-9568(1994)39:2<251:DRSOSA>2.0.ZU;2-X
Abstract
Densities, refractive indices, speeds of sound, and shear viscosities for the mixtures of diethylene glycol dimethyl ether with ethyl acetat e, methyl benzoate, ethyl benzoate, or diethyl succinate are measured as a function of mole fraction at temperatures of 298.15, 303.15, 308. 15, 313.15, and 318.15 K. The values of these properties are fitted to a power series equation involving both temperature and the mole fract ion of the mixture. The experimental values of the mixtures and pure l iquids are also used to calculate excess molar volume V(E), changes in isentropic compressibility DELTAbeta, changes in refractivity DELTAR, and changes in viscosity DELTAeta for the mixing process. These resul ts are fitted to the Redlich-Kister polynomial relation to estimate th e binary coefficients. The specific acoustic impedance factor of the l iquids has been calculated to see a possible match of their values wit h that of sea water, and the potential applications of these liquids a s sonar transducer fill fluids have been investigated. The refractive index and density values of the mixtures are used to test the accuracy of the available refractive index mixing relationships in predicting the binary refractive index data. Viscosity results are also analyzed by using the viscosity equations of McAllister, Heric, and Auslaender.