Ty. Makogon et Ed. Sloan, PHASE-EQUILIBRIUM FOR METHANE HYDRATE FROM 190-K TO 262-K, Journal of chemical and engineering data, 39(2), 1994, pp. 351-353
This work presents measurements on methane hydrate phase equilibrium i
n the three-phase region (ice + hydrate + vapor). Our results compleme
nt partial data sets from other laboratories and provide new results i
n the region 193-260 K. These data indicated that methane hydrate of s
tructure I does not undergo a phase transition to structure II as prop
osed in recent literature.