HYDROFORMYLATION IN THE PRESENCE OF A RHODIUM CATALYST PROMOTED BY SODIUM ALCOHOLATE

Authors
KORNEYEVA GA CHEKHOVA RV SLIVINSKII YV LOKTEV SM
Citation
Ga. Korneyeva et al., HYDROFORMYLATION IN THE PRESENCE OF A RHODIUM CATALYST PROMOTED BY SODIUM ALCOHOLATE, Petroleum chemistry, 33(6), 1993, pp. 509-515
Citations number
14
Categorie Soggetti
Energy & Fuels","Engineering, Chemical","Engineering, Petroleum
Journal title
Petroleum chemistry → ACNP
ISSN journal
09655441
Volume
33
Issue
6
Year of publication
1993
Pages
509 - 515
Database
ISI
SICI code
0965-5441(1993)33:6<509:HITPOA>2.0.ZU;2-B
Abstract
The effect of additive NaOR (R = CH3, C2H5, C4H9) on the rate and sele ctivity of hydroformylation of allyl alcohol and propene in the presen ce of unmodified and modified triphenylphosphine rhodium catalysts has been shown. The dependence of the indices of hydroformylation on the ratios Na/Rh and PPh3/Rh and the nature of R and also the results of a n IR spectral study of the catalytic complex indicate that the active Rh catalyst contains an OR group.